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For acetic acid (CH3COOH), the acid dissociation constant (Ka) is commonly given as about 1.8 × 10⁻⁵ at 25 °C. [1]
Ka is temperature-dependent because it’s derived from the equilibrium: CH3COOH ⇌ H⁺ + CH3COO⁻. Different references (and different temperatures like 0 °C vs 25 °C) report slightly different Ka values, even though they describe the same acid dissociation process. [1]
Because pKa = -log10(Ka), the Ka value above corresponds to a pKa of about 4.74 at 25 °C. [1]
If you need the base dissociation constant (Kb) for acetate (CH3COO⁻), it can be found using: Ka × Kb = Kw (where Kw ≈ 1.0 × 10⁻¹⁴ at 25 °C). Using Ka ≈ 1.8 × 10⁻⁵ gives Kb ≈ 5.6 × 10⁻¹⁰ at 25 °C. [1]
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